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A catalytic fluoride-rebound mechanism for C(sp(3))-CF(3) bond formation
The biological properties of trifluoromethyl compounds have led to their ubiquity in pharmaceuticals, yet their chemical properties have made their preparation a substantial challenge, necessitating innovative chemical solutions. We report the serendipitous discovery of a borane-catalyzed formal C(s...
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| Publicado no: | Science |
|---|---|
| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5902185/ https://ncbi.nlm.nih.gov/pubmed/28642435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aan1411 |
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