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Mechanism of Photoredox-Initiated C−C and C−N Bond Formation by Arylation of IPrAu(I)−CF(3) and IPrAu(I)−Succinimide

Herein, we report on the photoredox-initiated gold-mediated C(sp(2))−CF(3) and C(sp(2))−N coupling reactions. By adopting gold as a platform for probing metallaphotoredox catalysis, we demonstrate that cationic gold(III) complexes are the key intermediates of the C−C and C−N coupling reactions. The...

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Vydáno v:J Am Chem Soc
Hlavní autoři: Kim, Suhong, Toste, F. Dean
Médium: Artigo
Jazyk:Inglês
Vydáno: 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6446566/
https://ncbi.nlm.nih.gov/pubmed/30653314
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11273
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