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Mechanism of Photoredox-Initiated C−C and C−N Bond Formation by Arylation of IPrAu(I)−CF(3) and IPrAu(I)−Succinimide
Herein, we report on the photoredox-initiated gold-mediated C(sp(2))−CF(3) and C(sp(2))−N coupling reactions. By adopting gold as a platform for probing metallaphotoredox catalysis, we demonstrate that cationic gold(III) complexes are the key intermediates of the C−C and C−N coupling reactions. The...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6446566/ https://ncbi.nlm.nih.gov/pubmed/30653314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11273 |
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