Laddar...
Mechanism of Photoredox-Initiated C−C and C−N Bond Formation by Arylation of IPrAu(I)−CF(3) and IPrAu(I)−Succinimide
Herein, we report on the photoredox-initiated gold-mediated C(sp(2))−CF(3) and C(sp(2))−N coupling reactions. By adopting gold as a platform for probing metallaphotoredox catalysis, we demonstrate that cationic gold(III) complexes are the key intermediates of the C−C and C−N coupling reactions. The...
Sparad:
| I publikationen: | J Am Chem Soc |
|---|---|
| Huvudupphovsmän: | , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2019
|
| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6446566/ https://ncbi.nlm.nih.gov/pubmed/30653314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b11273 |
| Taggar: |
Lägg till en tagg
Inga taggar, Lägg till första taggen!
|