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C(sp(3))–F reductive elimination from alkylgold(iii) fluoride complexes
Rare examples of C(sp(3))–F reductive elimination were observed from several cis-F(2)Au(R)(IPr) intermediates generated by oxidation of (IPr)AuR complexes with XeF(2). For R groups bearing β-hydrogens, β-hydride elimination was competitive with C(sp(3))–F reductive elimination. For strained cyclic R...
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| Glavni autori: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3474378/ https://ncbi.nlm.nih.gov/pubmed/23087810 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00515D |
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