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Mechanism of C–F Reductive Elimination from Palladium(IV) Fluorides

The first systematic mechanism study of C–F reductive elimination from a transition metal complex is described. C–F bond formation from three different Pd(IV) fluoride complexes was mechanistically evaluated. The experimental data suggest that reductive elimination occurs from cationic Pd(IV) fluori...

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Detalhes bibliográficos
Main Authors: Furuya, Takeru, Benitez, Diego, Tkatchouk, Ekaterina, Strom, Alexandra E., Tang, Pingping, Goddard, William A., Ritter, Tobias
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2852535/
https://ncbi.nlm.nih.gov/pubmed/20196595
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja909371t
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