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Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)
[Image: see text] Two unique organometallic halide series (Ph(3)P)Au(4-Me-C(6)H(4))(CF(3))(X) and (Cy(3)P)Au(4-F-C(6)H(4))(CF(3))(X) (X = I, Br, Cl, F) have been synthesized. The PPh(3)-supported complexes can undergo both C(aryl)–X and C(aryl)–CF(3) reductive elimination. Mechanistic studies of the...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2015
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4482415/ https://ncbi.nlm.nih.gov/pubmed/26065722 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04613 |
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