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Halide-Dependent Mechanisms of Reductive Elimination from Gold(III)

[Image: see text] Two unique organometallic halide series (Ph(3)P)Au(4-Me-C(6)H(4))(CF(3))(X) and (Cy(3)P)Au(4-F-C(6)H(4))(CF(3))(X) (X = I, Br, Cl, F) have been synthesized. The PPh(3)-supported complexes can undergo both C(aryl)–X and C(aryl)–CF(3) reductive elimination. Mechanistic studies of the...

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書目詳細資料
發表在:J Am Chem Soc
Main Authors: Winston, Matthew S., Wolf, William J., Toste, F. Dean
格式: Artigo
語言:Inglês
出版: American Chemical Society 2015
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4482415/
https://ncbi.nlm.nih.gov/pubmed/26065722
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04613
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