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C(sp(3))–F reductive elimination from alkylgold(iii) fluoride complexes

Rare examples of C(sp(3))–F reductive elimination were observed from several cis-F(2)Au(R)(IPr) intermediates generated by oxidation of (IPr)AuR complexes with XeF(2). For R groups bearing β-hydrogens, β-hydride elimination was competitive with C(sp(3))–F reductive elimination. For strained cyclic R...

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Bibliographic Details
Main Authors: Mankad, Neal P., Toste, F. Dean
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3474378/
https://ncbi.nlm.nih.gov/pubmed/23087810
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00515D
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