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Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF(3)(+), CF(3)(•), and CF(3)(–) Reactivity
[Image: see text] Here we report the synthesis and application of trifluoromethyl thianthrenium triflate (TT-CF(3)(+)OTf(–)) as a novel trifluoromethylating reagent, which is conveniently accessible in a single step from thianthrene and triflic anhydride. We demonstrate the use of TT-CF(3)(+)OTf(–)...
Shranjeno v:
| izdano v: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical
Society
2021
|
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8297735/ https://ncbi.nlm.nih.gov/pubmed/33985330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c02606 |
| Oznake: |
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