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Rh(III)-Catalyzed Imidoyl C–H Carbamylation and Cyclization to Bicyclic [1,3,5]Triazinones

A Rh(III)-catalyzed synthesis of bicyclic [1,3,5]triazinones from a diverse array of imines coupled with ethyl (pivaloyloxy)carbamate is reported. The preparation of [5,6]- and [6,6]-bicyclic heterocycles substituted with aryl, alkyl and alkoxy groups demonstrated a broad reaction scope. The efficie...

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Bibliografische gegevens
Gepubliceerd in:Org Lett
Hoofdauteurs: Confair, Danielle N., Greenwood, Nathaniel S., Mercado, Brandon Q., Ellman, Jonathan A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2020
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7702018/
https://ncbi.nlm.nih.gov/pubmed/33172274
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c03393
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