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Rh(iii)-catalyzed diastereoselective C–H bond addition/cyclization cascade of enone tethered aldehydes

The Rh(iii)-catalyzed cascade addition of a C–H bond across alkene and carbonyl π-bonds is reported. The reaction proceeds under mild reaction conditions with low catalyst loading. A range of directing groups were shown to be effective as was the functionalization of alkenyl in addition to aromatic...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Boerth, Jeffrey A., Ellman, Jonathan A.
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2016
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4762265/
https://ncbi.nlm.nih.gov/pubmed/26918112
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04138d
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