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Highly Stereoselective Co(III)-Catalyzed Three-Component C–H Bond Addition Cascade

A highly stereoselective three-component C(sp(2))–H bond addition across alkene and polarized π-bonds is reported for which Co(III) catalysis was shown to be much more effective than Rh(III). The reaction proceeds at ambient temperature with both aryl and alkyl enones employed as efficient coupling...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Boerth, Jeffrey A., Hummel, Joshua R., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5039075/
https://ncbi.nlm.nih.gov/pubmed/27305062
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603831
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