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A Convergent Synthesis of Functionalized Alkenyl Halides via Co(III)-Catalyzed Three-Component C–H Bond Addition

A Co(III)-catalyzed three-component coupling of C(sp(2))–H bonds, alkynes, and halogenating agents to give alkenyl halides is reported. This transformation proceeds with high regio- and diastereoselectivity, and is effective for a broad range of aryl and alkyl terminal alkynes. Diverse C–H bond part...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Boerth, Jeffrey A., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5568819/
https://ncbi.nlm.nih.gov/pubmed/28657674
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705817
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