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Rh(III)-Catalyzed C–H Bond Addition/Amine-Mediated Cyclization of Bis-Michael Acceptors

A Rh(III)-catalyzed C–H bond addition/primary amine-promoted cyclization of bis-Michael acceptors is reported. The C–H bond addition step occurs with high chemoselectivity, and the subsequent intramolecular Michael addition, mediated by a primary amine catalyst, sets three contiguous stereocenters w...

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Bibliografiske detaljer
Udgivet i:Org Lett
Main Authors: Potter, Tyler J., Ellman, Jonathan A.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4975630/
https://ncbi.nlm.nih.gov/pubmed/27437933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01846
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