Janus Face All‐cis 1,2,4,5‐tetrakis(trifluoromethyl)‐ and All‐cis 1,2,3,4,5,6‐hexakis(trifluoromethyl)‐ Cyclohexanes

We report the synthesis of all‐cis 1,2,4,5‐tetrakis (trifluoromethyl)‐ and all‐cis 1,2,3,4,5,6‐hexakis (trifluoromethyl)‐ cyclohexanes by direct hydrogenation of precursor tetrakis‐ or hexakis‐ (trifluoromethyl)benzenes. The resultant cyclohexanes have a stereochemistry such that all the CF(3) group...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Yu, Cihang, Kütt, Agnes, Röschenthaler, Gerd‐Volker, Lebl, Tomas, Cordes, David B., Slawin, Alexandra M. Z., Bühl, Michael, O'Hagan, David
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2020
Ábhair:
Communications
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7693182/
https://ncbi.nlm.nih.gov/pubmed/32691941
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008662
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