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Organofluorine chemistry: Difluoromethylene motifs spaced 1,3 to each other imparts facial polarity to a cyclohexane ring

2,2-Dimethyl-5-phenyl-1,1,3,3-tetrafluororocyclohexane has been prepared and characterised as an example of a facially polarised cyclohexane containing 1,3 related CF(2) groups. The dipolar nature of the ring arises from the axial orientation of two of the C–F bonds pointing in the same direction, a...

詳細記述

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書誌詳細
出版年:Beilstein J Org Chem
主要な著者: Jones, Mathew J, Callejo, Ricardo, Slawin, Alexandra M Z, Bühl, Michael, O'Hagan, David
フォーマット: Artigo
言語:Inglês
出版事項: Beilstein-Institut 2016
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5238547/
https://ncbi.nlm.nih.gov/pubmed/28144355
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.281
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