α‐Functionalisation of Ketones Through Metal‐Free Electrophilic Activation

Triflic anhydride mediated activation of acetophenones leads to highly electrophilic intermediates that can undergo a variety of transformations when treated with nucleophiles. This electrophilic ketone activation gives access to α‐arylated and α‐oxyaminated acetophenones under metal‐free conditions...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Zawodny, Wojciech, Teskey, Christopher J., Mishevska, Magdalena, Völkl, Martin, Maryasin, Boris, González, Leticia, Maulide, Nuno
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7693173/
https://ncbi.nlm.nih.gov/pubmed/32914929
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006398
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