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Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles

A mild and metal-free regiodivergent addition of carbon nucleophiles to α,β-unsaturated electrophiles was developed. Total 1,2-regioselectivity was observed in the addition of nitrobenzyl chloride derivative 1 to α,β-unsaturated aldehydes 2 in the presence of TDAE. Moreover, the reaction between p-n...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Spitz, Cédric, Giuglio-Tonolo, Alain G., Terme, Thierry, Vanelle, Patrice
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6152382/
https://ncbi.nlm.nih.gov/pubmed/28708088
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules22071178
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