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Original Synthesis of Fluorenyl Alcohol Derivatives by Reductive Dehalogenation Initiated by TDAE

We report here a novel and easy-to-handle reductive dehalogenation of 9-bromofluorene in the presence of arylaldehydes and dicarbonyl derivatives to give the corresponding fluorenyl alcohol derivatives and Darzens epoxides as by-products in tetrakis(dimethylamino)ethylene (TDAE) reaction conditions....

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Giuglio-Tonolo, Alain Gamal, Terme, Thierry, Vanelle, Patrice
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6274501/
https://ncbi.nlm.nih.gov/pubmed/27783046
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules21101408
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