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Cationic NHC‐Phosphine Iridium Complexes: Highly Active Catalysts for Base‐Free Hydrogenation of Ketones

Novel bidentate N‐heterocyclic carbene‐phosphine iridium complexes have been synthesized and evaluated in the hydrogenation of ketones. Reported catalytic systems require base additives and, if excluded, need elevated temperature or high pressure of hydrogen gas to achieve satisfactory reactivity. T...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Quan, Xu, Kerdphon, Sutthichat, Peters, Bram B. C., Rujirawanich, Janjira, Krajangsri, Suppachai, Jongcharoenkamol, Jira, Andersson, Pher G.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7693092/
https://ncbi.nlm.nih.gov/pubmed/32678969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202002811
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