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Neutral iridium catalysts with chiral phosphine-carboxy ligands for asymmetric hydrogenation of unsaturated carboxylic acids

We developed neutral iridium catalysts with chiral spiro phosphine-carboxy ligands (SpiroCAP) for asymmetric hydrogenation of unsaturated carboxylic acids. Different from the cationic Crabtree-type catalysts, the iridium catalysts with chiral spiro phosphine-carboxy ligands are neutral and do not re...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yang, Shuang, Che, Wen, Wu, Hui-Ling, Zhu, Shou-Fei, Zhou, Qi-Lin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5384563/
https://ncbi.nlm.nih.gov/pubmed/28451313
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc03764j
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