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Kinetic resolution of racemic allylic alcohols via iridium-catalyzed asymmetric hydrogenation: scope, synthetic applications and insight into the origin of selectivity

Asymmetric hydrogenation is one of the most commonly used tools in organic synthesis, whereas, kinetic resolution via asymmetric hydrogenation is less developed. Herein, we describe the first iridium catalyzed kinetic resolution of a wide range of trisubstituted secondary and tertiary allylic alcoho...

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Publicat a:Chem Sci
Autors principals: Wu, Haibo, Margarita, Cristiana, Jongcharoenkamol, Jira, Nolan, Mark D., Singh, Thishana, Andersson, Pher G.
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179068/
https://ncbi.nlm.nih.gov/pubmed/34163958
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05276k
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