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Oxidative Addition of Water, Alcohols, and Amines in Palladium Catalysis

The homolytic cleavage of O−H and N−H or weak C−H bonds is a key elementary step in redox catalysis, but is thought to be unfeasible for palladium. In stark contrast, reported here is the room temperature and reversible oxidative addition of water, isopropanol, hexafluoroisopropanol, phenol, and ani...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Grünwald, Annette, Heinemann, Frank W., Munz, Dominik
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7692900/
https://ncbi.nlm.nih.gov/pubmed/32745317
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008350
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