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Formation of Transient Anionic Metal Clusters in Palladium/Diene‐Catalyzed Cross‐Coupling Reactions
Despite their considerable practical value, palladium/1,3‐diene‐catalyzed cross‐coupling reactions between Grignard reagents RMgCl and alkyl halides AlkylX remain mechanistically poorly understood. Herein, we probe the intermediates formed in these reactions by a combination of electrospray‐ionizati...
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| Publicado no: | Chemistry |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7687115/ https://ncbi.nlm.nih.gov/pubmed/31335999 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902610 |
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