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Second Comes First: Switching Elementary Steps in Palladium‐Catalyzed Cross‐Coupling Reactions
The electron‐poor palladium(0) complex L(3)Pd (L=tris[3,5‐bis(trifluoromethyl)phenyl]phosphine) reacts with Grignard reagents RMgX and organolithium compounds RLi via transmetalation to furnish the anionic organopalladates [L(2)PdR](−), as shown by negative‐ion mode electrospray‐ionization mass spec...
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| 出版年: | Chemistry |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
John Wiley and Sons Inc.
2020
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7540703/ https://ncbi.nlm.nih.gov/pubmed/32428266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202001041 |
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