Selective Pd-Catalyzed Monoarylation of Small Primary Alkyl Amines through Backbone-Modification in Ylide-Functionalized Phosphines (YPhos)

[Image: see text] Ylide-substituted phosphines have been shown to be excellent ligands for C–N coupling reactions under mild reaction conditions. Here we report studies on the impact of the steric demand of the substituent in the ylide-backbone on the catalytic activity. Two new YPhos ligands with b...

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Bibliografiske detaljer
Udgivet i:J Org Chem
Main Authors: Rodstein, Ilja, Prendes, Daniel Sowa, Wickert, Leon, Paaßen, Maurice, Gessner, Viktoria H.
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2020
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7684579/
https://ncbi.nlm.nih.gov/pubmed/32907331
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c01771
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