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Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature
Palladium allyl, cinnamyl, and indenyl complexes with the ylide‐substituted phosphines Cy(3)P(+)−C(−)(R)PCy(2) (with R=Me (L1) or Ph (L2)) and Cy(3)P(+)−C(−)(Me)PtBu(2) (L3) were prepared and applied as defined precatalysts in C−N coupling reactions. The complexes are highly active in the amination...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7186839/ https://ncbi.nlm.nih.gov/pubmed/31971642 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905535 |
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