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Palladium Complexes Based on Ylide‐Functionalized Phosphines (YPhos): Broadly Applicable High‐Performance Precatalysts for the Amination of Aryl Halides at Room Temperature

Palladium allyl, cinnamyl, and indenyl complexes with the ylide‐substituted phosphines Cy(3)P(+)−C(−)(R)PCy(2) (with R=Me (L1) or Ph (L2)) and Cy(3)P(+)−C(−)(Me)PtBu(2) (L3) were prepared and applied as defined precatalysts in C−N coupling reactions. The complexes are highly active in the amination...

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Foilsithe in:Chemistry
Main Authors: Tappen, Jens, Rodstein, Ilja, McGuire, Katie, Großjohann, Angela, Löffler, Julian, Scherpf, Thorsten, Gessner, Viktoria H.
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2020
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7186839/
https://ncbi.nlm.nih.gov/pubmed/31971642
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201905535
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