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1,2-Boron Shifts of β-Boryl Radicals Generated from Bis-Boronic Esters using Photoredox Catalysis

1,2-Bis-boronic esters are versatile intermediates that enable the rapid elaboration of simple alkene precursors. Previous reports on their selective mono-functionalization have targeted the most accessible position, retaining the more hindered secondary boronic ester. In contrast, we have found tha...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:J Am Chem Soc
Prif Awduron: Kaiser, Daniel, Noble, Adam, Fasano, Valerio, Aggarwal, Varinder K.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2019
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC7610657/
https://ncbi.nlm.nih.gov/pubmed/31461622
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b07564
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