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Alkynyl Moiety for Triggering 1,2‐Metallate Shifts: Enantiospecific sp(2)–sp(3) Coupling of Boronic Esters with p‐Arylacetylenes
The enantiospecific coupling of secondary and tertiary boronic esters to aromatics has been investigated. Using p‐lithiated phenylacetylenes and a range of boronic esters coupling has been achieved by the addition of N‐bromosuccinimide (NBS). The alkyne functionality of the intermediate boronate com...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5577510/ https://ncbi.nlm.nih.gov/pubmed/28618129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703894 |
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