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Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide

The reactions of laser‐ablated beryllium atoms with dinitrogen and carbon monoxide mixtures form the end‐on bonded NNBeCO and side‐on bonded (η(2)‐N(2))BeCO isomers in solid argon, which are predicted by quantum chemical calculations to be almost isoenergetic. The end‐on bonded complex has a triplet...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Deng, Guohai, Pan, Sudip, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7589277/
https://ncbi.nlm.nih.gov/pubmed/32583528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007241
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