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Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide

The reactions of laser‐ablated beryllium atoms with dinitrogen and carbon monoxide mixtures form the end‐on bonded NNBeCO and side‐on bonded (η(2)‐N(2))BeCO isomers in solid argon, which are predicted by quantum chemical calculations to be almost isoenergetic. The end‐on bonded complex has a triplet...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Deng, Guohai, Pan, Sudip, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7589277/
https://ncbi.nlm.nih.gov/pubmed/32583528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202007241
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