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Octa-coordinated alkaline earth metal–dinitrogen complexes M(N(2))(8) (M=Ca, Sr, Ba)
We report the isolation and spectroscopic identification of the eight-coordinated alkaline earth metal–dinitrogen complexes M(N(2))(8) (M=Ca, Sr, Ba) possessing cubic (O(h)) symmetry in a low-temperature neon matrix. The analysis of the electronic structure reveals that the metal-N(2) bonds are main...
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| Publicat a: | Nat Commun |
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| Autors principals: | , , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Nature Publishing Group UK
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6662891/ https://ncbi.nlm.nih.gov/pubmed/31358748 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-11323-5 |
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