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Transition‐Metal Chemistry of Alkaline‐Earth Elements: The Trisbenzene Complexes M(Bz)(3) (M=Sr, Ba)

We report the synthesis and spectroscopic identification of the trisbenzene complexes of strontium and barium M(Bz)(3) (M=Sr, Ba) in low‐temperature Ne matrix. Both complexes are characterized by a D (3) symmetric structure involving three equivalent η(6)‐bound benzene ligands and a closed‐shell sin...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Wang, Qian, Pan, Sudip, Wu, Yan‐Bo, Deng, Guohai, Bian, Jian‐Hong, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6900055/
https://ncbi.nlm.nih.gov/pubmed/31498532
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908572
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