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CO‐Induced Dinitrogen Fixation and Cleavage Mediated by Boron
The boron atoms react with carbon monoxide and dinitrogen forming the end‐on bonded NNBCO complex in solid neon or in nitrogen matrices. The NNBCO complex rearranges to the (η (2)‐N(2))BCO isomer with a more activated side‐on bonded dinitrogen ligand upon visible light excitation. (η (2)‐N(2))BCO an...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7898689/ https://ncbi.nlm.nih.gov/pubmed/32990332 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202004357 |
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