Caught in the H(inact): Crystal Structure and Spectroscopy Reveal a Sulfur Bound to the Active Site of an O(2)‐stable State of [FeFe] Hydrogenase

[FeFe] hydrogenases are the most active H(2) converting catalysts in nature, but their extreme oxygen sensitivity limits their use in technological applications. The [FeFe] hydrogenases from sulfate reducing bacteria can be purified in an O(2)‐stable state called H(inact). To date, the structure and...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Rodríguez‐Maciá, Patricia, Galle, Lisa M., Bjornsson, Ragnar, Lorent, Christian, Zebger, Ingo, Yoda, Yoshitaka, Cramer, Stephen P., DeBeer, Serena, Span, Ingrid, Birrell, James A.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540559/
https://ncbi.nlm.nih.gov/pubmed/32488975
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005208
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