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Highly Selective β-Mannosylations and β-Rhamnosylations Catalyzed by a Bis-thiourea
We report highly β-selective bis-thiourea-catalyzed 1,2-cis-O-pyranosylations employing easily accessible acetonide-protected donors. A wide variety of alcohol nucleophiles, including complex natural products, glycosides, and amino acids were β-mannosylated and rhamnosylated successfully using an op...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7523191/ https://ncbi.nlm.nih.gov/pubmed/32527078 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04255 |
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