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Stereoselective β-mannosylations and β-rhamnosylations from glycosyl hemiacetals mediated by lithium iodide

Stereoselective β-mannosylation is one of the most challenging problems in the synthesis of oligosaccharides. Herein, a highly selective synthesis of β-mannosides and β-rhamnosides from glycosyl hemi-acetals is reported, following a one-pot chlorination, iodination, glycosylation sequence employing...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Pongener, Imlirenla, Pepe, Dionissia A., Ruddy, Joseph J., McGarrigle, Eoghan M.
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8317664/
https://ncbi.nlm.nih.gov/pubmed/34377400
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01300a
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