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A Convergent Total Synthesis of the Potent Cephalostatin/Ritterazine Hybrid -25-epi Ritterostatin G(N)1(N)
The convergent synthesis of 25-epi ritterostatin G(N)1(N) is described for the first time, starting from hecogenin acetate (HA). Stereoselective dihydroxylation employing the chiral ligand (DHQ)(2)PHAL was used as the key step to introduce the C25 epi-stereocenter on the north 1 segment. The title c...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7511990/ https://ncbi.nlm.nih.gov/pubmed/23899273 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401171q |
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