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Synthesis of C14,15-Dihydro-C22,25-epi North Unit of Cephalostatin 1 via “Red-Ox” Modifications of Hecogenin Acetate
[Image: see text] C14,15-Dihydro-C22,25-epi north unit of cephalostatin 1 has been synthesized in eleven operations from a commercially available hecogenin acetate via multiple reductions and oxidations. The key transformations include: i) Cr(VI)-catalyzed E-ring opening, ii) C17 hydroxylation, and...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2859694/ https://ncbi.nlm.nih.gov/pubmed/19055428 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802122p |
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