Oxidation, Coordination, and Nickel‐Mediated Deconstruction of a Highly Electron‐Rich Diboron Analogue of 1,3,5‐Hexatriene

The reductive coupling of an N‐heterocyclic carbene (NHC) stabilized (dibromo)vinylborane yields a 1,2‐divinyldiborene, which, although isoelectronic to a 1,3,5‐triene, displays no extended π conjugation because of twisting of the C(2)B(2)C(2) chain. While this divinyldiborene coordinates to copper(...

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發表在:Angew Chem Int Ed Engl
Main Authors: Hermann, Alexander, Fantuzzi, Felipe, Arrowsmith, Merle, Zorn, Theresa, Krummenacher, Ivo, Ritschel, Benedikt, Radacki, Krzysztof, Engels, Bernd, Braunschweig, Holger
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2020
主題:
Research Articles
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497145/
https://ncbi.nlm.nih.gov/pubmed/32449598
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006131
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