A carregar...
Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling
The addition of Lewis bases to a cyclic (alkyl)(amino)carbene (CAAC)-supported dihydroboron triflate yields the mixed doubly base-stabilised dihydroboryl cations [(CAAC)BH(2)L](+). Of these, [(CAAC)(2)BH(2)]OTf (OTf = triflate) underwent facile two-electron reduction with KC(8) owing to a 1,2-hydrid...
Na minha lista:
| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7069503/ https://ncbi.nlm.nih.gov/pubmed/32206272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05026d |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|