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Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments
The M-(η(2)-BMn) complex [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(Cl)(tBu)Au(PPh(3))}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(R)(tBu)Au(PPh(3))}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh(3))...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5729409/ https://ncbi.nlm.nih.gov/pubmed/29403636 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00211g |
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