Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments

The M-(η(2)-BMn) complex [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(Cl)(tBu)Au(PPh(3))}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η(5)-C(5)H(5))(OC)(2)Mn{μ-B(R)(tBu)Au(PPh(3))}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh(3))...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Braunschweig, Holger, Radacki, Krzysztof, Shang, Rong
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2015
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5729409/
https://ncbi.nlm.nih.gov/pubmed/29403636
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00211g
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