Načítá se...

Reversible Borylene Formation from Ring Opening of Pinacolborane and Other Intermediates Generated from Five-Coordinate Tris-Boryl Complexes: Implications for Catalytic C–H Borylation

Catalytic C–H borylation using the five-coordinate tris-boryl complex (dippe)Ir(Bpin)(3) (5a, dippe = 1,2-bis(diisopropylphosphino)ethane) has been examined using (31)P{(1)H} and (1)H NMR spectroscopy. Compound 5a was shown to react rapidly and reversibly with HBpin to generate a six-coordinate bory...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Organometallics
Hlavní autoři: Ghaffari, Behnaz, Vanchura, Britt A., Chotana, Ghayoor A., Staples, Richard J., Holmes, Daniel, Maleczka, Robert E., Smith, Milton R.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2015
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5297890/
https://ncbi.nlm.nih.gov/pubmed/28190912
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00525
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!