A carregar...
Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane
LCuOTf complexes [L = cyclic (alkyl)(amino)carbenes (CAACs) or N-heterocyclic carbenes (NHCs)] selectively promote the dehydrogenative borylation of C(sp)–H bonds at room temperature. It is shown that σ,π-bis(copper) acetylide and copper hydride complexes are the key catalytic species.
Na minha lista:
| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5308285/ https://ncbi.nlm.nih.gov/pubmed/28451161 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02668k |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|