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Rhodium-Catalyzed Dehydrogenative Borylation of Cyclic Alkenes

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented.

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Detalhes bibliográficos
Main Authors: Kondoh, Azusa, Jamison, Timothy F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2825324/
https://ncbi.nlm.nih.gov/pubmed/20107646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b921387b
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