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Nickel-Catalyzed Allylic Substitution of Simple Alkenes

This report describes a nickel-catalyzed allylic substitution process of simple alkenes whereby an important structural motif, a 1,4-diene, was prepared. A key for this success is the use of an appropriate Ni-phosphine complex and a stoichiometric amount of silyl triflate. Reactions of 1-alkyl-subst...

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Detalhes bibliográficos
Main Authors: Matsubara, Ryosuke, Jamison, Timothy F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3224962/
https://ncbi.nlm.nih.gov/pubmed/21387565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/asia.201000875
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