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Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

Five-coordinate boryl complexes relevant to Ir mediated C–H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.

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Detalhes bibliográficos
Main Authors: Chotana, Ghayoor A., Vanchura, Britt A., Tse, Man Kin, Staples, Richard J., Maleczka, Robert E., Smith, Milton R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3573368/
https://ncbi.nlm.nih.gov/pubmed/19774251
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b914736e
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