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Active Intermediates in Copper Nitrite Reductase Reactions Probed by a Cryotrapping‐Electron Paramagnetic Resonance Approach

Redox active metalloenzymes catalyse a range of biochemical processes essential for life. However, due to their complex reaction mechanisms, and often, their poor optical signals, detailed mechanistic understandings of them are limited. Here, we develop a cryoreduction approach coupled to electron p...

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Dettagli Bibliografici
Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Hedison, Tobias M., Shanmugam, Muralidharan, Heyes, Derren J., Edge, Ruth, Scrutton, Nigel S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2020
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7497095/
https://ncbi.nlm.nih.gov/pubmed/32352195
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202005052
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